pH and pOH

Rucete ✏ Chemistry In a Nutshell

1. What Is pH?

  • pH measures the hydrogen ion concentration [H⁺] in a solution.
  • Formula: pH = -log[H⁺]

2. What Is pOH?

  • pOH measures the hydroxide ion concentration [OH⁻] in a solution.
  • Formula: pOH = -log[OH⁻]

3. Relationship Between pH and pOH

  • pH and pOH are related through water’s ion product constant (Kw).
  • pH + pOH = 14
  • [H⁺][OH⁻] = 1.0 × 10⁻¹⁴

4. Interconverting [H⁺], [OH⁻], pH, and pOH

  • If you know one value (e.g., pH), you can calculate the others using:
    • pH = -log[H⁺]
    • pOH = -log[OH⁻]
    • pH + pOH = 14

5. Acidic and Basic Ranges

  • Acidic solution: pH < 7
  • Neutral solution: pH = 7
  • Basic solution: pH > 7

In a nutshell

Low pH = More H⁺ = Acidic!

  • pH down → [H⁺] up
  • pH up → [OH⁻] up
  • pH + pOH = 14

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