Salts

Rucete ✏ Chemistry In a Nutshell

1. What Is a Salt?

  • A salt is formed when an acid reacts with a base.
  • General reaction:
    Acid + Base → Salt + Water
  • Example:
    HCl + NaOH → NaCl + H₂O
  • NaCl here is the salt.

2. Salts as Strong Electrolytes

  • Many salts are strong electrolytes, meaning they dissociate completely in water, producing ions that affect pH.

3. Salt Hydrolysis and pH

  • When salts dissolve in water, they can affect the pH depending on the ions formed.
  • Key rule:
    • Conjugate base of a strong acid (e.g., Cl⁻, Br⁻, NO₃⁻) → neutral
    • Cation from a weak base (e.g., NH₄⁺) → acidic
    • Anion from a weak acid (e.g., HCO₃⁻, F⁻) → basic

4. Types of Salts and Their pH Effects

  • Neutral salts: from a strong acid + strong base
    • Example: NaCl
  • Acidic salts: from a strong acid + weak base
    • Example: NH₄Cl
  • Basic salts: from a weak acid + strong base
    • Example: NaHCO₃

5. Factors That Affect Salt Behavior in Solution

  • Type of ions (cation/anion)
  • Solubility of the salt
  • Temperature of the solution
  • Concentration of the salt

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